Received: February 06, 2018; Published: February 16, 2018
Corresponding author: Linghai XIE, Center for Molecular Systems & Organic Devices (CMSOD), Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing, 210023, China, Tel: 86 187 5187 6505; Email: firstname.lastname@example.org
In the background of the era of consciousness (EOC) from carbon to robot, we proposed an alternative way via the nanoarchitectures to challenge suspended issues from plastic electronics. Covalent meta-molecules with the features of structural diversity, hierarchy and cross-scale have absolute advantages to decode the universe law of matter and to explore the advanced materials. In the past decade, we focus on a versatile C (sp3)- C (sp2) reaction of fluorenol’sFrediel-Crafts protocol (FOH's FCP)  as a tool of molecular installing technology, associated with the Pd-catalyzed (sp2)- C (sp2) coupling reaction such as Suzuki cross-coupling reaction. A series of the complex di aryl fluorine's (CDAFs), have been synthesized, including small molecules, polymers, as well as covalent nanostructures via the An+Bn and/ or Ann modes where A represents for fluorine's (from Alcohol) and Before benzene substrates [2-8]. Recently, we discoverednano-gridarenes that is a huge family of organic unit nanogrids , multigrids  as well as polygrids  after the exploration of fluorine-based nano synthesis ten year age . Grid polymers serve as the advanced soluble nanopolymers with potential application of light-emitting diodes, lasers, solar cells and memory . In perspective, in the framework of systematically cross-scale and hierarchical chemistry, various meta-structures will be designed and fabricated from the range of zero-dimensional nanomolecules, one-dimensional nanopolymers via strong nano linkages, two-dimensional covalent organic frameworks, and 3D nano-architectures as well as fractal nanostructures via the fluorenol’snanosynthons, offering a series of state-of-the-art models and advanced materials.
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