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ISSN: 2637-4609

Archives of Organic and Inorganic Chemical Sciences

Research Article(ISSN: 2637-4609)

Heterobimetallic Aryloxides of Titanatranes with Aluminum Alkyls for Ring opening polymerization (ROP) of rac-Lactide

Volume 1 - Issue 2

Prabhuodeyara M Gurubasavaraj*

  • Author Information Open or Close
    • Department of Chemistry, Rani Channamma University, India

    *Corresponding author: Prabhuodeyara M Gurubasavaraj, Department of Chemistry, Rani Channamma University, PBNH-4 Vidyasangama, Belagavi-596156 India

Received: January 05, 2018;   Published: February 05, 2018

DOI: 10.32474/AOICS.2018.01.000110

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Abstract

The titanatrane titanium complexes were treated with Aluminum Alkyls to prepare their bimetallic derivatives (1a-4a). The compounds were confirmed by means of NMR and elemental analysis. The complexes were used as catalysts for ring opening polymerization of racemic lactide. The complexes exhibit high activity and selectivity in the polymerization process.

Abbrevations: ROP: Ring Opening Polymerization; LA: Rac-lactide

Abstract| Introduction| Results and Discussion| Experimental Section| References|

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